Abstract
用Hagihara脱氢卤代法合成了三种新的9,9-二(十六烷基)芴基二聚炔铂(d8)、金和汞(d10)化合物反式-[Pt(Ph)(PEt3)2C≡CRC≡CPt(Ph)(PEt3)2,[(PPh3)AuC≡CRC≡CAu(PPh3)]和[MeHgC≡CRC≡CHgMe][R=9,9-二(十六烷基)芴基].用1HNMR,13CNMR,31PNMR,FT-IR,FAB-MS,UV-Vis,荧光和磷光光谱对其进行了表征.结果表明,体系中的铂、金和汞产生的重原子效应可以有效地促进单线激发态S1与三线激发态T1的系间跃迁,使标题化合物产生有机三线态发光.
Translated title of the contribution | Synthesis and Properties of Pt, Au and Hg Complexes Coordinated with 9,9-Dihexadecylfluorene-2,7-diacetylide |
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Original language | Chinese (Simplified) |
Pages (from-to) | 884-888 |
Number of pages | 5 |
Journal | 化学学报 |
Volume | 64 |
Issue number | 9 |
Publication status | Published - Sept 2006 |
Scopus Subject Areas
- General Chemistry
User-Defined Keywords
- 9,9-dihexadecylfluorene-2,7-diacetylene
- Luminescence
- Phosphorescence
- Pt(II), Au(I) and Hg(II) coordination compound
- Synthesis
- 9,9-二(十六烷基)芴基二聚炔
- 铂、金和汞配合物
- 合成
- 荧光
- 磷光