9,9-二(十六烷基)芴基二聚炔铂、金和汞配合物的合成与性质

Translated title of the contribution: Synthesis and Properties of Pt, Au and Hg Complexes Coordinated with 9,9-Dihexadecylfluorene-2,7-diacetylide

柳利*, 陈祖兴, 柳士忠, 黄维扬

*Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

12 Citations (Scopus)

Abstract

用Hagihara脱氢卤代法合成了三种新的9,9-二(十六烷基)芴基二聚炔铂(d8)、金和汞(d10)化合物反式-[Pt(Ph)(PEt3)2C≡CRC≡CPt(Ph)(PEt3)2,[(PPh3)AuC≡CRC≡CAu(PPh3)]和[MeHgC≡CRC≡CHgMe][R=9,9-二(十六烷基)芴基].用1HNMR,13CNMR,31PNMR,FT-IR,FAB-MS,UV-Vis,荧光和磷光光谱对其进行了表征.结果表明,体系中的铂、金和汞产生的重原子效应可以有效地促进单线激发态S1与三线激发态T1的系间跃迁,使标题化合物产生有机三线态发光.
Translated title of the contributionSynthesis and Properties of Pt, Au and Hg Complexes Coordinated with 9,9-Dihexadecylfluorene-2,7-diacetylide
Original languageChinese (Simplified)
Pages (from-to)884-888
Number of pages5
Journal化学学报
Volume64
Issue number9
Publication statusPublished - Sept 2006

Scopus Subject Areas

  • General Chemistry

User-Defined Keywords

  • 9,9-dihexadecylfluorene-2,7-diacetylene
  • Luminescence
  • Phosphorescence
  • Pt(II), Au(I) and Hg(II) coordination compound
  • Synthesis
  • 9,9-二(十六烷基)芴基二聚炔
  • 铂、金和汞配合物
  • 合成
  • 荧光
  • 磷光

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