6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes

Chun Lin Deng; Xiao Dong Xiong; David T.W. Chik; Zongwei CAI; Xiao Shui Peng; Henry N.C. Wong

doi:10.1002/asia.201500689

6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes

Chun Lin Deng, Xiao Dong Xiong, David T.W. Chik, Zongwei CAI, Xiao Shui Peng, Henry N.C. Wong^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

10 Citations (Scopus)

Abstract

6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C₆₀ and C₇₀ in toluene.

Original language	English
Pages (from-to)	2342-2346
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	10
Issue number	11
DOIs	https://doi.org/10.1002/asia.201500689
Publication status	Published - 1 Nov 2015

User-Defined Keywords

fullerenes
host-guest chemistry
macrocycles
synthesis
tetraphenylene

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title = "6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes",

abstract = "6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C60 and C70 in toluene.",

keywords = "fullerenes, host-guest chemistry, macrocycles, synthesis, tetraphenylene",

author = "Deng, {Chun Lin} and Xiong, {Xiao Dong} and Chik, {David T.W.} and Zongwei CAI and Peng, {Xiao Shui} and Wong, {Henry N.C.}",

note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2015",

month = nov,

day = "1",

doi = "10.1002/asia.201500689",

language = "English",

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TY - JOUR

T1 - 6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles

T2 - Synthesis, Structures, and Complexation with Fullerenes

AU - Deng, Chun Lin

AU - Xiong, Xiao Dong

AU - Chik, David T.W.

AU - CAI, Zongwei

AU - Peng, Xiao Shui

AU - Wong, Henry N.C.

PY - 2015/11/1

Y1 - 2015/11/1

N2 - 6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C60 and C70 in toluene.

AB - 6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C60 and C70 in toluene.

KW - fullerenes

KW - host-guest chemistry

KW - macrocycles

KW - synthesis

KW - tetraphenylene

UR - http://www.scopus.com/inward/record.url?scp=84945467457&partnerID=8YFLogxK

U2 - 10.1002/asia.201500689

DO - 10.1002/asia.201500689

M3 - Journal article

C2 - 26211744

AN - SCOPUS:84945467457

SN - 1861-4728

VL - 10

SP - 2342

EP - 2346

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 11

ER -

6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes

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