TY - JOUR
T1 - 2-[(1E,4E)-4-(2-Methoxy-phen-yl)-3H-benzo[b][1,5]diazepin-2-yl]phenol
AU - Zia-Ul-Haq, Muhammad
AU - Munir, Arshad
AU - Qadeer, Ghulam
AU - Rama, Nasim Hasan
AU - WONG, Wai Yeung
N1 - Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2007/8
Y1 - 2007/8
N2 - The asymmetric unit of the title compound, C22H18N2O2, contains two crystallographically independent mol-ecules, in which each mol-ecule is composed of three planar six-membered rings and one nonplanar seven-membered ring. The six-membered A (phenol), B (fused benzene) and C (methoxyphenyl) rings are oriented with respect to each other at dihedral angles of 88.79 (3) (A/B), 68.16 (3) (A/C) and 37.51 (2)° (B/C), and 82.43 (3) (A′/B′), 78.52 (2) (A′/C′) and 28.65 (3)° (B′/C′). The seven-membered rings adopt near-boat conformations. Intra-molecular O - H⋯N and C - H⋯O hydrogen bonds are present in the crystal structure.
AB - The asymmetric unit of the title compound, C22H18N2O2, contains two crystallographically independent mol-ecules, in which each mol-ecule is composed of three planar six-membered rings and one nonplanar seven-membered ring. The six-membered A (phenol), B (fused benzene) and C (methoxyphenyl) rings are oriented with respect to each other at dihedral angles of 88.79 (3) (A/B), 68.16 (3) (A/C) and 37.51 (2)° (B/C), and 82.43 (3) (A′/B′), 78.52 (2) (A′/C′) and 28.65 (3)° (B′/C′). The seven-membered rings adopt near-boat conformations. Intra-molecular O - H⋯N and C - H⋯O hydrogen bonds are present in the crystal structure.
UR - http://www.scopus.com/inward/record.url?scp=34547757945&partnerID=8YFLogxK
U2 - 10.1107/S1600536807034824
DO - 10.1107/S1600536807034824
M3 - Journal article
AN - SCOPUS:34547757945
SN - 1600-5368
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
M1 - o3600
ER -