双膦钌配合物Ru(OAc)2(Ph3P)(dppm)和Ru(OAc)2(dppm)2的合成和催化性能

null 高景星; null 万惠霖; Rick W K 黄伟国

双膦钌配合物Ru(OAc)₂(Ph₃P)(dppm)和Ru(OAc)₂(dppm)₂的合成和催化性能

Translated title of the contribution: Synthesis and Catalytic Activity of Ru(OAc)₂(Ph₃P)(dppm) and Ru(OAc)₂(dppm)₂

高景星, 万惠霖, 黄伟国

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

Abstract

合成了双膦醋酸钌配合物,不同温度的1H NMR谱表明,两个醋酸根分别以单齿和双齿配体与中心钌(Ⅱ)配位;31P NMR和X-射线结构分析表明膦配体为面式构型.配合物对丙烯酸和苯乙烯有选择氢化活性.

Interacting Ru(OAc)₂(Ph₃P)with dppm(bis(diphenylphosphino)methane)in refluxing toluene gave Ru(OAc)₂(Ph₃P)(dppm) and Ru(OAc)₂(dppm)₂ in yields of 79% and 8l%, respectively.¹H NMR study carried out at various temperatures showed that the two acetates are coordinated to the central Ru(Ⅱ) in forms of monodentate and didentate.³¹PNMR and X-ray diffractometric results revealed the fac-configuration of phosphine ligands.Under hydrogen pressures of 1.0～4.0MPa and temperatures 30～70℃, the title complexes showed a catalytic activity to the selective hydrogenation of acrylic acid and styrene.

Translated title of the contribution	Synthesis and Catalytic Activity of Ru(OAc)₂(Ph₃P)(dppm) and Ru(OAc)₂(dppm)₂
Original language	Chinese (Simplified)
Pages (from-to)	5-8
Number of pages	4
Journal	应用化学
Volume	12
Issue number	3
Publication status	Published - 10 Jun 1995

User-Defined Keywords

双膦配体
钌配合物
丙烯酸
苯乙烯
氢化
diphosphine ligand
ruthenium complex
acrylic acid
styrene
hydrogenation

Cite this

@article{651aef6ebac14e269940a915e0fca7d3,

title = "双膦钌配合物Ru(OAc)2(Ph3P)(dppm)和Ru(OAc)2(dppm)2的合成和催化性能",

abstract = "合成了双膦醋酸钌配合物,不同温度的1H NMR谱表明,两个醋酸根分别以单齿和双齿配体与中心钌(Ⅱ)配位;31P NMR和X-射线结构分析表明膦配体为面式构型.配合物对丙烯酸和苯乙烯有选择氢化活性.Interacting Ru(OAc)2(Ph3P)with dppm(bis(diphenylphosphino)methane)in refluxing toluene gave Ru(OAc)2(Ph3P)(dppm) and Ru(OAc)2(dppm)2 in yields of 79% and 8l%, respectively.1H NMR study carried out at various temperatures showed that the two acetates are coordinated to the central Ru(Ⅱ) in forms of monodentate and didentate.31PNMR and X-ray diffractometric results revealed the fac-configuration of phosphine ligands.Under hydrogen pressures of 1.0～4.0MPa and temperatures 30～70℃, the title complexes showed a catalytic activity to the selective hydrogenation of acrylic acid and styrene.",

keywords = "双膦配体, 钌配合物, 丙烯酸, 苯乙烯, 氢化, diphosphine ligand, ruthenium complex, acrylic acid, styrene, hydrogenation",

author = "高景星 and 万惠霖 and 黄伟国",

year = "1995",

month = jun,

day = "10",

language = "Chinese (Simplified)",

volume = "12",

pages = "5--8",

journal = "应用化学",

issn = "1000-0518",

publisher = "Science Press",

number = "3",

}

TY - JOUR

T1 - 双膦钌配合物Ru(OAc)2(Ph3P)(dppm)和Ru(OAc)2(dppm)2的合成和催化性能

AU - 高景星, null

AU - 万惠霖, null

AU - 黄伟国, null

PY - 1995/6/10

Y1 - 1995/6/10

N2 - 合成了双膦醋酸钌配合物,不同温度的1H NMR谱表明,两个醋酸根分别以单齿和双齿配体与中心钌(Ⅱ)配位;31P NMR和X-射线结构分析表明膦配体为面式构型.配合物对丙烯酸和苯乙烯有选择氢化活性.Interacting Ru(OAc)2(Ph3P)with dppm(bis(diphenylphosphino)methane)in refluxing toluene gave Ru(OAc)2(Ph3P)(dppm) and Ru(OAc)2(dppm)2 in yields of 79% and 8l%, respectively.1H NMR study carried out at various temperatures showed that the two acetates are coordinated to the central Ru(Ⅱ) in forms of monodentate and didentate.31PNMR and X-ray diffractometric results revealed the fac-configuration of phosphine ligands.Under hydrogen pressures of 1.0～4.0MPa and temperatures 30～70℃, the title complexes showed a catalytic activity to the selective hydrogenation of acrylic acid and styrene.

AB - 合成了双膦醋酸钌配合物,不同温度的1H NMR谱表明,两个醋酸根分别以单齿和双齿配体与中心钌(Ⅱ)配位;31P NMR和X-射线结构分析表明膦配体为面式构型.配合物对丙烯酸和苯乙烯有选择氢化活性.Interacting Ru(OAc)2(Ph3P)with dppm(bis(diphenylphosphino)methane)in refluxing toluene gave Ru(OAc)2(Ph3P)(dppm) and Ru(OAc)2(dppm)2 in yields of 79% and 8l%, respectively.1H NMR study carried out at various temperatures showed that the two acetates are coordinated to the central Ru(Ⅱ) in forms of monodentate and didentate.31PNMR and X-ray diffractometric results revealed the fac-configuration of phosphine ligands.Under hydrogen pressures of 1.0～4.0MPa and temperatures 30～70℃, the title complexes showed a catalytic activity to the selective hydrogenation of acrylic acid and styrene.

KW - 双膦配体

KW - 钌配合物

KW - 丙烯酸

KW - 苯乙烯

KW - 氢化

KW - diphosphine ligand

KW - ruthenium complex

KW - acrylic acid

KW - styrene

KW - hydrogenation

UR - http://yyhx.ciac.jl.cn/CN/Y1995/V0/I3/5

UR - http://yyhx.ciac.jl.cn/EN/Y1995/V0/I3/5

M3 - Journal article

SN - 1000-0518

VL - 12

SP - 5

EP - 8

JO - 应用化学

JF - 应用化学

IS - 3

ER -

双膦钌配合物Ru(OAc)₂(Ph₃P)(dppm)和Ru(OAc)₂(dppm)₂的合成和催化性能

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