Abstract
综述了近年来我们研究小组在双模式路易斯酸介导的串联反应研究方面的进展. 利用双模式路易斯酸的特殊性 质, 发展了三种新的串联环化反应, 并通过拓展反应起始底物的方式对方法学的底物适用性进行了探究, 最后, 将方 法学应用至天然产物全合成的研究之中.
This account covers the recent advance of the dual-mode Lewis acid induced cascade cyclization reactions in our group. Taking advantage of the special properties of the dual-mode Lewis acids, three new types of cascade reactions have been developed. Moreover, the applicability of the cascade cyclization reactions was explored through studying the scope of substrates. Finally, these reactions were employed for total syntheses of natural products.
This account covers the recent advance of the dual-mode Lewis acid induced cascade cyclization reactions in our group. Taking advantage of the special properties of the dual-mode Lewis acids, three new types of cascade reactions have been developed. Moreover, the applicability of the cascade cyclization reactions was explored through studying the scope of substrates. Finally, these reactions were employed for total syntheses of natural products.
| Translated title of the contribution | Applications of Dual-Mode Lewis Acids Induced Cascade Cyclization Reactions in Natural Product Synthesis |
|---|---|
| Original language | Chinese (Simplified) |
| Pages (from-to) | 2031-2045 |
| Number of pages | 15 |
| Journal | 有机化学 |
| Volume | 33 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 25 Oct 2013 |
User-Defined Keywords
- 双模式路易斯酸
- 串联环化反应
- 天然产物全合成
- dual-mode Lewis acid
- cascade cyclization reaction
- total syntheses of natural product