σ-Acetylide complexes of ruthenium(IV) and osmium(IV) thiolates

Qian Feng Zhang; Chui Ying Lai; Wai Yeung Wong; Wa Hung Leung

doi:10.1021/om011019t

σ-Acetylide complexes of ruthenium(IV) and osmium(IV) thiolates

Qian Feng Zhang, Chui Ying Lai, Wai Yeung Wong, Wa Hung Leung^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › peer-review

22 Citations (Scopus)

Abstract

Treatment of [M(Sxylyl)₃(MeCN)Cl] (M = Ru, Os; xylyl = 2,6-dimethylphenyl) with PhC≡CH in the presence of Et₃N afforded [Et₃NH][M(Sxylyl)₃(C≡CPh)-Cl]. The crystal structure of [Et₃NH][Ru(Sxylyl)₃(C≡Ctol)Cl] (tol = 4-tolyl) has been determined. The average Ru-S, Ru-C, and Ru-Cl distances are 2.1980, 1.991-(5), and 2.5131(13) Å, respectively. Interaction of [Et₄-NH][Ru(Sxylyl)₃(C≡CPh)Cl] with excess t-BuNC gave trans-[Ru(t-BuNC)₄(Sxylyl)₂].

Original language	English
Pages (from-to)	4017-4020
Number of pages	4
Journal	Organometallics
Volume	21
Issue number	19
DOIs	https://doi.org/10.1021/om011019t
Publication status	Published - 16 Sept 2002

Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{edfb5a9c96bb47768fb04f3dcd04c53e,

title = "σ-Acetylide complexes of ruthenium(IV) and osmium(IV) thiolates",

abstract = "Treatment of [M(Sxylyl)3(MeCN)Cl] (M = Ru, Os; xylyl = 2,6-dimethylphenyl) with PhC≡CH in the presence of Et3N afforded [Et3NH][M(Sxylyl)3(C≡CPh)-Cl]. The crystal structure of [Et3NH][Ru(Sxylyl)3(C≡Ctol)Cl] (tol = 4-tolyl) has been determined. The average Ru-S, Ru-C, and Ru-Cl distances are 2.1980, 1.991-(5), and 2.5131(13) {\AA}, respectively. Interaction of [Et4-NH][Ru(Sxylyl)3(C≡CPh)Cl] with excess t-BuNC gave trans-[Ru(t-BuNC)4(Sxylyl)2].",

author = "Zhang, {Qian Feng} and Lai, {Chui Ying} and Wong, {Wai Yeung} and Leung, {Wa Hung}",

note = "This work has been supported by The Hong Kong University of Science and Technology and the Areas of Excellence Scheme established under the University Grants Committee of the Hong Kong Special Administrative Region, People's Republic of China (Project No. AoE/P-10/01-1). ",

year = "2002",

month = sep,

day = "16",

doi = "10.1021/om011019t",

language = "English",

volume = "21",

pages = "4017--4020",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - σ-Acetylide complexes of ruthenium(IV) and osmium(IV) thiolates

AU - Zhang, Qian Feng

AU - Lai, Chui Ying

AU - Wong, Wai Yeung

AU - Leung, Wa Hung

N1 - This work has been supported by The Hong Kong University of Science and Technology and the Areas of Excellence Scheme established under the University Grants Committee of the Hong Kong Special Administrative Region, People's Republic of China (Project No. AoE/P-10/01-1).

PY - 2002/9/16

Y1 - 2002/9/16

N2 - Treatment of [M(Sxylyl)3(MeCN)Cl] (M = Ru, Os; xylyl = 2,6-dimethylphenyl) with PhC≡CH in the presence of Et3N afforded [Et3NH][M(Sxylyl)3(C≡CPh)-Cl]. The crystal structure of [Et3NH][Ru(Sxylyl)3(C≡Ctol)Cl] (tol = 4-tolyl) has been determined. The average Ru-S, Ru-C, and Ru-Cl distances are 2.1980, 1.991-(5), and 2.5131(13) Å, respectively. Interaction of [Et4-NH][Ru(Sxylyl)3(C≡CPh)Cl] with excess t-BuNC gave trans-[Ru(t-BuNC)4(Sxylyl)2].

AB - Treatment of [M(Sxylyl)3(MeCN)Cl] (M = Ru, Os; xylyl = 2,6-dimethylphenyl) with PhC≡CH in the presence of Et3N afforded [Et3NH][M(Sxylyl)3(C≡CPh)-Cl]. The crystal structure of [Et3NH][Ru(Sxylyl)3(C≡Ctol)Cl] (tol = 4-tolyl) has been determined. The average Ru-S, Ru-C, and Ru-Cl distances are 2.1980, 1.991-(5), and 2.5131(13) Å, respectively. Interaction of [Et4-NH][Ru(Sxylyl)3(C≡CPh)Cl] with excess t-BuNC gave trans-[Ru(t-BuNC)4(Sxylyl)2].

UR - http://www.scopus.com/inward/record.url?scp=0038150331&partnerID=8YFLogxK

U2 - 10.1021/om011019t

DO - 10.1021/om011019t

M3 - Journal article

AN - SCOPUS:0038150331

SN - 0276-7333

VL - 21

SP - 4017

EP - 4020

JO - Organometallics

JF - Organometallics

IS - 19

ER -

σ-Acetylide complexes of ruthenium(IV) and osmium(IV) thiolates

Abstract

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